成品油管道内腐蚀影响因素分析及防控对策

Analysis of contributing factors to internal corrosion of refined oil pipelines and corresponding prevention and control measures

  • 摘要: 成品油管道的内腐蚀问题普遍存在,极易影响成品油的安全输送和油品质量,造成经济损失和安全隐患。为此,通过宏观测量分析、理化性能试验、清管产物分析等方法对成品油管道进行了内腐蚀影响因素的研究,提出了相应的防控对策。研究结果表明:1)腐蚀痕迹沿管道轴向分布,宽度约为80 mm,位于管道6:00方向,壁厚测量值均小于名义壁厚6.400 mm,局部位置腐蚀较为严重;2)跨腐蚀区域断后伸长率小于正常管体,拉伸承载能力下降了4.97%;3)管道内腐蚀由建设期的内腐蚀逐渐发展形成,建设期压力试验后清扫不彻底,存在积液,造成管道底部发生吸氧腐蚀;4)氯离子使溶液pH值降低,引发管道产生点蚀坑;5)成品油管道中的泥沙、结垢、铁锈等杂质会增大管道底部粗糙度,提高油品中游离水的吸附能力,导致水的积存,加剧管道内壁的电化学腐蚀。最后提出相应的防控对策:1)运行期管道可通过增加清管频率、注入缓蚀剂、优化油品性能来减缓内腐蚀速率;2)新建管道可通过选择耐腐蚀材质、增加内涂层、投产前清除试压余水等方法来有效控制管体腐蚀。

     

    Abstract: Internal corrosion is a common issue affecting refined oil pipelines, posing significant risks to the safe transportation and quality of refined oils, and potentially leading to economic losses and safety hazards. To address this problem, the contributing factors to internal corrosion in refined oil pipelines were investigated using multiple methods, including macroscopic measurements and analysis, physical and chemical performance experiments, and pigging product analysis. Based on the results of these analyses, corresponding prevention and control measures were proposed. The study results are summarized as follows: 1) Corrosion traces are distributed axially, covering a width of approximately 80 mm and located at the six o'clock position along the pipe. All wall thickness measurements are below the nominal wall thickness of 6.400 mm, and exacerbated corrosion was observed at localized positions. 2) The elongation after fracture in the sample affected by corrosion is reduced compared to that in the normal pipe sample, with the tensile bearing capacity dropping by 4.97%. 3) The internal corrosion of the refined oil pipeline originated from the construction period and developed gradually over time. Particularly, oxygen-consuming corrosion occurred at the bottom of the pipeline during construction, resulting from liquid loading due to insufficient pigging after pressure testing. 4) Chloride ions reduce the pH value of the solution, leading to the formation of corrosion pits in the pipe. 5) Impurities such as silt, scale, and rust in the refined oil pipeline roughen the bottom of the pipeline, thereby increasing the capacity to trap free water in the oils. This accumulation of water intensifies electrochemical corrosion on the inner wall of the pipeline. Corresponding prevention and control measures are proposed as follows: 1) The internal corrosion rate of pipelines can be reduced during operation by increasing the frequency of pigging, injecting corrosion inhibitors, and optimizing oil properties. 2) Corrosion is controlled for new pipelines by selecting corrosion-resistant materials, applying additional inner coatings, and ensuring the removal of residual water from pressure testing before commissioning.

     

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