多种杂质对超临界/密相CO2物性的影响机制

Influencing mechanisms of various impurities on the physical properties of supercritical/dense-phase CO2

  • 摘要: CO2输送是连接碳捕集、利用与封存(carbon capture,utilization and storage,CCUS)产业链上下游的枢纽环节。受碳源与捕集方式差异的影响,管道输送的CO2中常含有多种杂质,其种类与含量会显著影响CO2的物性。对此,首先分析了纯CO2的物性与相态变化规律,明确了超临界/密相为CO2大规模长距离输送的首选相态;其次基于状态方程,结合气体间相互作用、临界温度和压力模型以及气液平衡方程,计算了含杂质CO2的物性。研究表明,掺入摩尔分数小于5%的CH4、N2、CO等杂质可有效降低CO2的临界温度与临界压力,最优输送工况压力约为14 MPa、温度在临界温度附近。通过多元回归分析并结合状态方程,发现杂质对CO2临界温度和临界压力的影响与其自身的临界温度和压力呈正相关,而在杂质摩尔分数低于5%时,对CO2密度、黏度等物性变化的整体影响较小。在管道输送过程中,应重点关注杂质对CO2临界温度和临界压力的影响。本研究可为超临界/密相CO2的大规模、长距离、安全高效管道输送提供设计依据与理论基础。

     

    Abstract: CO2 transport is a crucial component linking the upstream and downstream segments of the Carbon Capture, Utilization and Storage (CCUS) industry chain. Due to variations in carbon sources and capture methods, pipeline-transported CO2 often contains various impurities, which can significantly impact its physical properties. In this study, the physical properties and phase behavior of pure CO2 were analyzed at first, confirming that the supercritical/dense-phase was optimal for large-scale, long-distance transport. Using the equation of state, gas interaction models, critical temperature and pressure models, and the gas-liquid equilibrium equation, the physical properties of CO2 with impurities were calculated. Results indicated that adding impurities such as CH4, N2, and CO at molar fractions below 5% effectively lowered the critical temperature and pressure of CO2. The optimal transport conditions were approximately 14 MPa and a temperature near the critical point. Multiple regression analysis, combined with the equation of state, revealed that the influence of impurities on CO2's critical temperature and pressure was positively correlated with the impurities' own critical parameters. When the molar fraction of impurities was less than 5%, their overall impact on CO2 properties such as density and viscosity was minimal. For pipeline transport, particular attention should be given to the effects of impurities on the critical temperature and pressure of CO2. This study provides design basis and theoretical foundation for the safe, efficient, and large-scale transport of supercritical/dense-phase CO2 by pipeline.

     

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