吸附-吸收-膜法在成品油储油库油气回收处理中的应用

Application of adsorption-absorption-membrane process for oil vapor recovery at refined oil depots

  • 摘要: 面对日益严格的挥发性有机物(VOCs)排放标准,现有储油库“吸附-吸收”法油气回收工艺已难以满足深度治理需求。本研究以某实际成品油储运库为对象,提出并实施了一种“吸附-吸收-膜”法组合工艺改造方案。通过在油气收集系统增设引风机建立微负压环境,并在原有工艺末端集成以聚辛基甲基硅氧烷/聚丙烯腈(POMS/PAN)复合膜为核心的精处理单元,实现了油气的深度回收与超低排放。工程实践表明,该组合工艺可将非甲烷总烃(NMHC)排放浓度由吸附后的25 g/m3稳定降至9.88 g/m3以下,降幅超过60%。该方案创新性地实现了吸附法高负荷处理能力与膜法高精度分离优势的协同,并有效控制了改造成本,为现有油库升级油气回收设施提供了技术可行、经济合理的方案。

     

    Abstract: Facing increasingly stringent volatile organic compound (VOCs) emission standards, the conventional"adsorption-absorption "process for oil vapor recovery in existing oil depots no longer meets advanced treatment requirements. This study focuses on a refined oil storage and transportation depot, proposing and implementing a retrofitted" adsorption-absorption-membrane "hybrid process. An induced draft fan was added to the vapor collection system to create a slight negative pressure, and a refining unit based on a poly (octylmethylsiloxane)/polyacrylonitrile (POMS/PAN) composite membrane was integrated at the end of the original process, enabling deep recovery and ultra-low oil vapor emissions. Engineering results indicated that the hybrid process consistently reduced non-methane total hydrocarbon (NMHC) emissions from 25 g/m3 after adsorption to below 9.88 g /m3, achieving over 60% reduction. This approach innovatively combines the high-capacity adsorption with the precise separation of membrane technology while effectively controlling retrofit costs, offering a technically viable and economically sound solution for upgrading oil vapor recovery systems in existing oil depots.

     

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